This is the cover of the “Complete Edtion” of Mobile Suit Gundam 00 The Movie – A Wakening of the Trailblazer -.
I beleive the artwork is by Kanetake Ebikawa, who designed all of the ‘O’* series mecha for the show.
The other releases of the Home Video release will feature covers designed by Seiichi Nakatani, another mecha designer for the series and Michinori Chiba, series Character Designer.
The film will be available for purchace (in Japan Only) on Christmas.
Additional Details regarding that can be found here.
* NOTE: ‘O’ series is a extremely shortform designation for “all of the Gundams that Setsuna pilots”.
But to better clarify, Ebikawa designed all of Setsuna’s units (the Exia, the 00 Gundam and the 00 QAN[T]). He also designed the Astraea, which is featured in many of the Gundam 00 Sidestories. All of these Mobile Suits designs trace back to the O Gundam, Celestial Being’s first Mobile Suit.
Source Pic: HappinetOnline